有機化学特論Ⅰ - 理学系研究科 - 東京大学授業カタログ

有機化学特論Ⅰ

遷移金属触媒反応：Transition-metal catalyzed reactions

最近のノーベル化学賞授賞対象となった不斉還元・酸化反応，メタセシス反応，クロスカップリング反応の発見の経緯・反応機構を中心に概説し，これらを鍵反応として用いる医薬品・機能性材料の合成法について紹介する。
The history of discovery and reaction mechanism of asymmetric, metatheses, and cross-coupling reactions will be shown．
Synthesis of drug medicines and functional materials based on these reactions will be also reviewed.

MIMA Search

授業計画

Innovation of C-C and C=C coupling reactions I : Pd-Catalyzed C-C cross coupling reactions II : Olefin metathesis reaction New Methodologies for C-C and C-Si Bond Forming Reactions Using Anionic Transition Metal Complexes as Active Catalytic Species I : New Methodology for Nucleophilic Activation of Olefin Ligands II : A New Methodology for Generation of Alkyl Radical Species III : A New Cross-Coupling Reaction Using Alkyl Halides New Interconnecting Methods for Molecular Devices by Coupling Reaction I : New Methodology for Manufacture of Nano Photo Switching Device II : New Synthetic Methodologies of Insulated Molecular Wires

授業の方法

対面あるいはオンライン講義 Lecture or Online Lecture by ZOOM

成績評価方法

出席とレポートによる attendance & submitting a term paper Evaluation will be based on class attendance (50%) and six times 10-min. short exam (50%) during lecture.

教科書

教科書は使用せず，プリントを配布する handouts

参考書

John F. Hartwig, Organotransition Metal Chemistry: From Bonding to Catalysis

履修上の注意

After each lecture, we're going to have a quiz. The results of the question will contain an attendance point and have some effect on your grade. And, I'm going to hand out some copies. Please fill suitable words or compound structures in the blank space.

その他

開講日など詳細は，以下の化学専攻HPを確認してください。 Please refer to the below link for details about lecture date. http://www.chem.s.u-tokyo.ac.jp/*****