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最終更新日：2026年10月16日

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Materials, Systems and Dynamics V

Electron spin and chemical reactivity
This course is concerned with the influence that quantum mechanical electron spin can have on the rate and yield of chemical reactions. The course focuses on reaction intermediates known as Spin Correlated Radical Pairs (SCRPs) and discusses their importance, particularly in photochemistry, focussing on how they allow chemical reactions to respond to magnetic fields. The course will cover the Radical Pair Mechanism in detail, including quantum mechanical treatments based on the density matrix formalism. The significance of SCRPs to important biological problems such as animal navigation and the influence of environmental electromagnetic fields on human health will be discussed.
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時間割／共通科目コード
コース名
教員
学期
時限
31D360-0290S
GAS-ES6D05L3
Materials, Systems and Dynamics V
ウッドワード　ジョナサン　ロジャー
S1 S2
火曜2限
マイリストに追加
マイリストから削除
講義使用言語
英語
単位
2
実務経験のある教員による授業科目
NO
他学部履修
可
開講所属
総合文化研究科
授業計画
1) A refresher on angular momentum, spin and photochemistry 2) Solution phase reaction dynamics 3) Diffusion controlled reactions, magnetic interactions and an introduction to radical pairs 4) The Radical Pair Mechanism 5) Revisiting bra / ket notation 6) Quantum mechanics of electron spin 7) Basic quantum mechanics of radicals and radical pairs 8) Quantum mechanics of radical pairs 9) Density matrices, time evolution, Monte Carlo approach 10) Liouville Space, Spinach and the Stochastic Liouville equation 11) Magnetic field effects in biology 12) and 13) Student presentations and feedback
授業の方法
This class uses a combination of conventional interactive lectures and live coding sessions. There will be coursework assignments consisting of problem sets, coding challenges and literature research.
成績評価方法
Grades will be awarded based on coursework assignments, a presentation and an in-class multiple choice test.
履修上の注意
This course is conducted entirely in English The class will be delivered face-to-face and assignments will be announced in class and made available on UTOL.
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