Lecture 1. Course introduction
Lecture 2. Hydrogen atom spectra and the Bohr model of the atom.
Lecture 3. Quantum mechanics - wavefunctions, Born interpretation, normalization, 3 dimensions. Restrictions on the wavefunction, operators, Schrodinger, Heisenberg Uncertainty Principle.
Lecture 4. Particle in a box.
Lecture 5. Angular momentum. H atom - Solution to the Schrodinger equation, spin.
Lecture 6. s, p and d orbitals, radial distribution functions. Many electron atoms. Pauli exclusion principle.
Lecture 7. Penetration and shielding, Aufbau, Hund, periodic table, ionization energies. Chemical bonding, Valence bond model, hybridization.
Lecture 8. MO Theory, bonding and antibonding orbitals, homonuclear diatomics, bond order and magnetism, heteronuclear diatomics, electronegativity, frontier orbitals.
Lecture 9. Ideal Gas Law, Kinetic theory of gases, Maxwell Boltzmann distribution, intermolecular forces.
Lecture 10. Polarizability, induced dipoles and dispersion interactions, hydrogen bonding. Modes of energy storage - translation, rotation, vibration, electronic energy, heat capacity, equipartition, the Boltzmann distribution.
Lecture 11. Introduction to chemical thermodynamics. Enthalpy, standard enthalpies, Hess’s law
Lecture 12. Helmholtz energy, Gibbs energy, chemical potential,
Lecture 13. Chemical equilibria, equilibrium constants