Chemical Thermodynamics I (GSC)

In this lecture, basics of chemical thermodaynamics such as equation of state, real systems, and Boltzmann distribution, with addition of advanced topics such as phonon modes will be taught. The lecture will be conveyed in collaboration by staff members of solid state physical chemistry laboratory including, A. Namai (associate professor), K. Nakabayashi (assistant professor), K. Imoto (assistant professor), M. Yoshikiyo (assistant professor), and O. Stefanczyk (assistant professor).

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授業計画

・Introduction ・Virial equation and Van der Waals’ equation of state ・Critical phenomenon and critical point ・Real systems, Berthelot’s equation and Dieterici’s equation ・Diathermic and adiabatic walls and molecular theory interpretation of internal energy ・Configurations and weights, Boltzmann distribution (statistical thermodynamics, Boltzmann distribution law, molecular partition function) ・Thermodynamics of chemical reaction ・Chemical potential ・Phase diagrams (Lever rule, solid solution, Zone melting method) ・Superfluidity phenomenon (Bose–Einstein condensation) ・Thermodynamics relations ・Concept of fugacity ・Mixing of materials

授業の方法

Lecture

成績評価方法

Attendence, mid-term exam, end-term exam

教科書

Self-produced text book is to be distributed.

参考書

Atkins' Physical Chemistry

履修上の注意

Lectures will be done in English, but Japanese version textbooks will also be handed out for reference. Students are required to prepare for and review the lecture using the distributed textbooks.