有機化学特論II

本講義では，前半ではこれまでに履修したアニオンおよびカチオン以外の反応活性種について論じる．すなわ ち，ラジカルカチオンとラジカルアニオン，フリーラジカルとラジカル連鎖，カルベンとカルベン錯体，また有機金属錯体の構造と反応などについて学ぶ．後半 では，有機金属反応とペリ環状反応について概説する．有機化学I-IIIで履修した内容を前提とする．講義スケジュールは以下の通りである．
前半
１．中性分子：分子軌道，一電子酸化と一電子還元
２．ラジカルカチオンとラジカルアニオン：構造と反応性
３．フリーラジカル：構造，安定性，発生法，ラジカル連鎖反応と合成的応用
４．カルベン：構造と金属錯体
５．有機金属活性種
後半
１．周辺環状反応
２．電子環状反応
３．付加環化反応
４．Pdを用いた有機金属反応とその応用
５．Znを用いた有機金属反応とその応用

In this class, you will learn reactive chemical species in addition to anion and cations in the S1 term. The materials cover the structure and reactivity of radical cations, radical anions, free radicals, carbenes, carbene complexes, and organometallics. Afterwards, in the S2 term, you will learn basis of organometallic reactions and pericyclic reactions. You are supposed to master the contents of the classes of Organic Chemistry I–III. More specifically, the class will cover the following content:
In the S1 term,
(1) Neutral molecules: molecular orbitals, single-electron oxidation and single-electron reduction.
(2) Radical cations and radical anions: structure and reactivity.
(3) Free radicals: structure, stability, reactivity, generation methods, chain reactions, and synthetic applications.
(4) Carbenes: Structure and their metal complexes
(5) Reactive organometallic species
In the S2 term,
(1) Pericyclic reactions.
(2) Electrocyclic reactions.
(3) Cycloaddition reactions.
(4) Organometallic reactions using Pd and their applications
(5) Organometallic reactions using Zn and their applications