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過去(2022年度)の授業の情報です
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最終更新日:2024年3月15日

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有機化学基礎I

有機化学基礎I/ Basic Organic Chemistry I
1. Subjects of this class
The following basic concepts of organic chemistry will be introduced.
(1)Understand the concept of electron-donation and withdrawal (Hammett rule) using molecular orbital theory
(2)Structure and molecular orbitals of non-classical carbocations
(3)Recent progress of supramolecular chemistry and molecular assembly
(4)Introduction of molecular orbital calculations and evaluation of accuracy
(5)Kinetics, thermodynamics, selectivity, effect of metal catalyst in aldol reaction
(6)Carbon-carbon bond fission of carbonyl compounds by photoreaction
(7)Structure and reactivity of main-group and transition-metal complexes
(8)Structure and reactivity of ate complexes and related molecules
(9)Catalytic cycle for hydrogenation of alkene and cross-coupling reaction using homogeneous catalyst
MIMA Search
時間割/共通科目コード
コース名
教員
学期
時限
35606-0054
GSC-CH5207L3
有機化学基礎I
磯部 寛之
S1
火曜3限
マイリストに追加
マイリストから削除
講義使用言語
英語
単位
1
実務経験のある教員による授業科目
NO
他学部履修
開講所属
理学系研究科
授業計画
4. Schedule: Do NOT share/distribute URLs over SNS or other Internet media. April 5, 19, 26, 28 [13:15–14:45] (1) April 5 (HI): Orientation https://bit.ly/***** (2) April 19 (HI): conjugated systems/molecular structures (Chapters 2,3 of Ed 1/2) https://bit.ly/***** (3) April 26 (HI): organic reactions I/reactive intermediates/supramolecular chem (Chapters 4,5 of Ed1; Chapters 11,4 of Ed2) https://bit.ly/***** (4) April 28 (HI w/Ikemoto): Exam #1 CAUTION: Styles of exams should be announced later. [Face-to-face/Online/Hybrid] tentative URL for "online" https://bit.ly/***** (5) May 10 (RS): Chapter 6, Chapter 7 and 8 (organic reactions II, ate complex, hypervalent and low-valent compounds) https://bit.ly/***** (6) May 17 (RS): Chapter 9 and 10 (effect of ligand in catalysis, trans effect, oxidative addition/reductive elimination) https://bit.ly/***** (7) May 24 (RS): Exam #2 https://bit.ly/***** (NOTICE: Please send an email with the title "BOC-1 2022" to "*****" before May 10. In the email sent to Dr. Shang, please inform your name and student ID ***** will send you documents for the BOC class by replying your email.) When revised, URLs should be made available at ITC-LMS and/or UTAS.
授業の方法
Online (zoom) For Shang's classes on May 10, May 17, and May 24 Classes = Online classes via ZOOM. Topic: BOC-1 Class by Rui Shang https://u-tokyo-ac-jp.zoom.us/***** Meeting ID: ***** Passcode: ***** (NOTICE: Please send an email with the title "BOC-1 2022" and your name and student ID **********", before May 10. Dr. Shang will send you documents for the BOC class by replying your email)
成績評価方法
3. Exam and grading Two exams (50 points each). Those who score over 50 points will be credited. Exams of BOC-1 Class by Rui Shang = The examination will be arranged online via ZOOM. Schedule of online ZOOM examination: the exam will start from 13:00 to 14:45 on May 24. Student should attend the exam via ZOOM meeting. The exam questions will be distributed via email after checking attendance on ZOOM. Students are asked to answer the exam questions on an A4 answer sheet (white A4 papers prepared by yourself in advance) with the ZOOM video on in the assigned time period. The ZOOM exam starts from 13:00 on May 24 and the students should send their scanned answer sheet (or photo of your answer sheet taken by your mobile phone) to ***** by 15:00 on May 24. If you have problem to receive the exam questions in your email address or you have questions during the examination, you can directly raise your hand and talk to Dr. Shang on ZOOM. (If you realize you will have difficulty to connect to ZOOM on May 24, please send an email to ***** with a subject BOC-1-Shang-Exam to clarify your situation) Questions = basically will be related with the contents discussed in the classes and will partly be covered by “practice exercises” distributed via email after the classes on May 10th and May 17th. If you have any health problem that causes you difficulty to attend the online class, please send me an email with title BOC-1-Shang-Class on that day to clarify your situation, otherwise you will be recorded as “ABSENT”.
教科書
2. Textbook 「大学院講義有機化学(東京化学同人,野依良治編)」I巻, 第1版(基本) (“Organic Chemistry for Graduate Students” Volume 1, 1st edition, Japanese edition only)
参考書
General Reference Books: “March’s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure”, Michael B. Smith and Jerry March (up to fifth edition) “Advanced Organic Chemistry, Part A: Structure and Mechanisms; Part B: Reaction and Synthesis”, Francis A. Carey and Richard J. Sundberg Specific textbooks will be recommended in class at the respective chapter.
履修上の注意
none